Sanguiin H 11
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Casuarictin is an
ellagitannin The ellagitannins are a diverse class of hydrolyzable tannins, a type of polyphenol formed primarily from the oxidative linkage of galloyl groups in 1,2,3,4,6-pentagalloyl glucose. Ellagitannins differ from gallotannins, in that their galloyl group ...
, a type of hydrolysable tannin. It can be found in ''
Casuarina ''Casuarina'' is a genus of 17 tree species in the family Casuarinaceae, native to Australia, the Indian subcontinent, southeast Asia, islands of the western Pacific Ocean, and eastern Africa. It was once treated as the sole genus in the fami ...
'' and ''
Stachyurus ''Stachyurus'' is the only genus in the flowering plant family Stachyuraceae, native to the Himalayas and eastern Asia. They are deciduous shrubs or small trees with pendent racemes of 4-petalled flowers which appear on the bare branches before t ...
'' species.Tannins of Casuarina and Stachyurus species. I: Structures of pendunculagin, casuarictin, strictinin, casuarinin, casuariin, and stachyurin. Okuda T., Yoshida T., Ashida M. and Yazaki K., Journal of the Chemical Society, 1983, number 8, pages 1765-1772, It is formed from two
hexahydroxydiphenic acid Hexahydroxydiphenic acid is an organic compound with the formula HO)3C6HCO2Hsub>2. It is the oxidatively coupled derivative of gallic acid It is a white solid, although samples are typically brown owing to oxidation. left, 142px, Ellagic acid. ...
units and one
gallic acid Gallic acid (also known as 3,4,5-trihydroxybenzoic acid) is a trihydroxybenzoic acid with the formula C6 H2( OH)3CO2H. It is classified as a phenolic acid. It is found in gallnuts, sumac, witch hazel, tea leaves, oak bark, and other plants. It i ...
unit linked to a
glucose Glucose is a simple sugar with the molecular formula . Glucose is overall the most abundant monosaccharide, a subcategory of carbohydrates. Glucose is mainly made by plants and most algae during photosynthesis from water and carbon dioxide, using ...
molecule. The molecule is formed from
tellimagrandin II Tellimagrandin II is the first of the ellagitannins formed from 1,2,3,4,6-pentagalloyl-glucose. It can be found in '' Geum japonicum'' and ''Syzygium aromaticum'' (clove).Purification and Characterization of Eugeniin as an Anti-herpesvirus Compound ...
, itself formed from pentagalloyl glucose via oxidation. Casuarictin is transformed into
pedunculagin Pedunculagin is an ellagitannin. It is formed from casuarictin via the loss of a gallate group. Natural occurrence Pedunculagin is found in plants in orders in the clade Rosidae. It can be found the pericarp of pomegranates (''Punica granatum ...
via loss of a gallate group, and further into
castalagin Castalagin is an ellagitannin, a type of hydrolyzable tannin, found in oak and chestnut wood and in the stem barks of '' Anogeissus leiocarpus'' and ''Terminalia avicennoides''. Castalagin is the diastereomer of vescalagin in C-1 of the glycosidi ...
via glucose pyranose ring opening.


Oligomers

Sanguiin H-6 Sanguiin H-6 is an ellagitannin. Natural occurrence Sanguiin H-6 can be found in Rosaceae such as the great burnet (''Sanguisorba officinalis''), in strawberries (''Fragaria × ananassa'') and in ''Rubus'' species such as red raspberries (''Rub ...
is a dimer,
Lambertianin C Lambertianin C is an ellagitannin. Natural occurrence Lambertianin C can be found in ''Rubus'' species such as '' Rubus lambertianus'', in cloudberries (''Rubus chamaemorus'') and in red raspberries (''Rubus idaeus''). Chemistry Lambertianin ...
is trimer and
lambertianin D Lambertianin D is an ellagitannin found in ''Rubus lambertianus''. It is tetramer of casuarictin linked by sanguisorbic acid Sanguisorbic acid is a constituent of some ellagitannins. It is constituted by a hexahydroxydiphenic acid unit linked by ...
is a tetramer of casuarictin.


References

{{Ellagitannin Ellagitannins Lactones